Electrical conductivity (EC) is a property that is used to describe how well materials allow electrons to flow. It is determined using experiments and math equations. Conductivity is the reciprocal of resistivity, meaning the higher the conductivity, the lower the resistivity. A conductor is a material that has a high electrical conductivity, and an insulator is a material that has a high electrical resistivity. Both properties depend on the temperature and purity of materials.
Temperature dependence of electrical conductivity follows a general pattern. Metal is a conductor, and it has lower conductivity at higher temperatures. Glass is an insulator and shows higher conductivity at higher temperatures.
At very high temperatures, conductors behave like insulators, and insulators behave like conductors. This behavior of insulators and conductors is explained by the free electron model. In this model, conductors clearly show the ability to free electrons, and when a current, or electric force, is applied, the force can easily push around the extra electrons.
Soil is a mixture of minerals, salts and organic materials. It has a special electrical conductivity called soil electrical conductivity, which measures the amount of salt that is in a soil sample, which is called its salinity. The process can also measure other soil properties where salinity is low enough. These properties are related to the influence that purity has on EC data.
EC data of a soil sample can determine how much impurity is in the soil. Soil impurities are water, air and minerals. Each impurity influences the data differently, but a practiced soil scientist can determine this information from the gathered data. In general, more impurities lower the EC, with the exception of minerals that increase EC. Impurities also can explain the use of pure copper in electrical wiring.
Metals are often made of alloys, a mixture of two or more elements. This is not useful for conducting electricity. The metals in alloys are not the same elements and electrons cannot flow easily between different elements. Pure metals, such as copper wire, have high electricalconductivity. This applies only to solid metals because air pockets can lower the electricalconductivity of materials.
Materials that are not metals usually make good insulators. The best insulators are materials that naturally have air pockets in them, such as rubber. The air pockets are like impurities and disrupt the flow of electrons. Gases, such as air, are the best natural insulators. Modern chemistry has mastered insulators, creating materials that have thousands of times more resistivity than air.
Source / Courtesy : WiseGeek